------------------------------------------------------------------------------ MSDS for ACETONITRILE-D3 Page 1 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------ PRODUCT NAME: ACETONITRILE-D3 FORMULA: CD3CN FORMULA WT: 44.07 CAS NO.: 02206-26-0 COMMON SYNONYMS: DEUTERATED ACETONITRILE PRODUCT CODES: A164 EFFECTIVE: 08/27/86 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 2 MODERATE FLAMMABILITY - 3 SEVERE (FLAMMABLE) REACTIVITY - 2 MODERATE CONTACT - 2 MODERATE HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER PRECAUTIONARY LABEL STATEMENTS WARNING FLAMMABLE HARMFUL IF INHALED OR ABSORBED THROUGH SKIN KEEP AWAY FROM HEAT, SPARKS, FLAME. AVOID CONTACT WITH EYES, SKIN, CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE. FLUSH SPILL AREA WITH WATER SPRAY. SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE) ------------------------------------------------------------------------------ 2 - HAZARDOUS COMPONENTS ------------------------------------------------------------------------------ COMPONENT % CAS NO. ACETONITRILE-D3 90-100 2206-26-0 ------------------------------------------------------------------------------ 3 - PHYSICAL DATA ------------------------------------------------------------------------------ BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A ------------------------------------------------------------------------------ MSDS for ACETONITRILE-D3 Page 2 ------------------------------------------------------------------------------ SPECIFIC GRAVITY: 0.84 EVAPORATION RATE: N/A (H2O=1) (BUTYL ACETATE=1) SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100 APPEARANCE & ODOR: COLORLESS LIQUID WITH ETHER-LIKE ODOR. ------------------------------------------------------------------------------ 4 - FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------ FLASH POINT (CLOSED CUP: 6 C ( 42 F) NFPA 704M RATING: 2-3-1 FLAMMABLE LIMITS: UPPER - 16 % LOWER - 4.2 % FIRE EXTINGUISHING MEDIA USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.) SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. TOXIC GASES PRODUCED HYDROGEN CYANIDE ------------------------------------------------------------------------------ 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------ TOXICITY TEST RESULTS AND HEALTH EFFECTS ARE BASED ON THE NON-DEUTERATED PRODUCT. THRESHOLD LIMIT VALUE (TLV/TWA): 70 MG/M3 ( 40 PPM) SHORT-TERM EXPOSURE LIMIT (STEL): 105 MG/M3 ( 60 PPM) PERMISSIBLE EXPOSURE LIMIT (PEL): 70 MG/M3 ( 40 PPM) TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 3800 LD50 (IPR-RAT)(MG/KG) - 850 LD50 (IPR-MOUSE)(MG/KG) - 175 CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF OVEREXPOSURE VAPORS MAY BE IRRITATING TO SKIN, EYES, NOSE AND THROAT. INGESTION MAY CAUSE NAUSEA, VOMITING, PARALYSIS. TARGET ORGANS ------------------------------------------------------------------------------ MSDS for ACETONITRILE-D3 Page 3 ------------------------------------------------------------------------------ KIDNEYS, LIVER, CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM, LUNGS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INHALATION, INGESTION, ABSORPTION, SKIN CONTACT, EYE CONTACT EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. TLV LISTED DENOTES (TLV-SKIN). ------------------------------------------------------------------------------ 6 - REACTIVITY DATA ------------------------------------------------------------------------------ STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, FLAME, SOURCES OF IGNITION INCOMPATIBLES: STRONG ACIDS, STRONG OXIDIZING AGENTS DECOMPOSITION PRODUCTS: HYDROGEN CYANIDE, OXIDES OF NITROGEN ------------------------------------------------------------------------------ 7 - SPILL AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED FOR SPILLS OF THIS PRODUCT. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U003 (TOXIC WASTE) ------------------------------------------------------------------------------ 8 - PROTECTIVE EQUIPMENT ------------------------------------------------------------------------------ VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. ------------------------------------------------------------------------------ MSDS for ACETONITRILE-D3 Page 4 ------------------------------------------------------------------------------ RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 400 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED. EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE RECOMMENDED. ------------------------------------------------------------------------------ 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------ SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE) SPECIAL PRECAUTIONS BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA. ------------------------------------------------------------------------------ 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION ------------------------------------------------------------------------------ DOMESTIC (D.O.T.) PROPER SHIPPING NAME ACETONITRILE HAZARD CLASS FLAMMABLE LIQUID UN/NA NA1648 LABELS FLAMMABLE LIQUID REPORTABLE QUANTITY 5000 LBS. INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME METHYL CYANIDE HAZARD CLASS 3.2 UN/NA UN1648 LABELS FLAMMABLE LIQUID, POISON